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  • articleNo Access

    Flexible α-Fe2O3 nanorod electrode materials for sodium-ion batteries with excellent cycle performance

    With the rise of flexible electronics, flexible rechargeable batteries have attracted widespread attention as a promising power source in new generation flexible electronic devices. In this work, α-Fe2O3 nanorods grown on carbon cloth have been synthesized through a facile hydrothermal method as binder-free electrode material. The electrochemical performance measurements show that α-Fe2O3 nanorods possess high specific capacitance and specific capacity retention of 119% after 100 cycles. The combination of low-cost and excellent electrochemical performance makes α-Fe2O3 nanorods promising anode materials for sodium-ion batteries.

  • articleNo Access

    A novel solid electrolyte formed by NASICON-type Li3Zr2Si2PO12 and poly(vinylidene fluoride) for solid state batteries

    Owing to their high ionic conductivity and excellent flexibility, composite polymer electrolytes (CPEs) have been widely studied in solid lithium metal batteries (SLMBs). In this study, a new solid electrolyte of NASICON-type Li3Zr2Si2PO12 (LZSP) was prepared by the sol–gel method, and then a new type of CPE membrane containing LZSP and Poly(vinylidene fluoride) (PVDF) was synthesized by slurry-casting method. The CPE membrane presented much higher ionic conductivity of 5.66 × 105 S ⋅ cm1 at 25C and stronger electrochemical stability compared to the one without LZSP. In addition, the cells containing the composite electrolyte membrane exhibited considerable rate performance and cycle performance.

  • articleNo Access

    Improved cycling stability of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode materials by optimizing Ti doping

    Nickel-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) oxide is a prospective cathode material of Li-ion batteries owing to its high energy density and affordable price, however, it suffers from the poor cycling performance. The doping for metal cations is considered as an effective way to enhance its cycling stability. In this work, titanium was chosen to partially substitute transition-metal ions, i.e. Ni, Co and Mn, and the Ti content was optimized to improve the electrochemical performance of NCM811. The Ti-doped Li(Ni0.8Co0.1Mn0.1)1xTixO2 powder was prepared using high temperature solid-state synthesis. The layered α-NaFeO2-type structure of NCM811 survives in the doped samples, and the lattice parameters a and c increase linearly with the Ti content. XPS spectra indicate that the Ni ions show a mixing state of +2 and +3, and the portion of Ni2+ increases by the Ti doping. The cycling stability is improved evidently by a small amount of Ti doping, i.e. capacity retention of 88.3–96.9% for x = 0.01–0.03 versus 64.1% for x = 0 after 100 cycles at 0.1 C. Thus, the sample with x = 0.01 delivers the high discharge capacity of 180.6 mAh g1 after 100 cycles, much greater than 116.5 mAh g1 of x = 0. Nevertheless, more Ti doping with x = 0.04–0.05 deteriorates the electrochemical performance. It illustrates the presence of optimal Ti-doping range in NCM811, which was rationalized as the synergetic effects of bond strength, Li+ diffusion, chemical composition and valence state of cations.

  • articleNo Access

    FUTURE ASPECT OF REFRIGERANTS: CONSIDERING THERMOPHYSICAL PROPERTIES AND CYCLE PERFORMANCE

    Refrigeration, air conditioning and heat pump equipments (generally known as heat pumps) are very important for the civilized society. However, discharged refrigerants from heat pumps and exhausted carbon dioxide to drive heat pumps result in serious environmental problems. For this reason, fluorocarbon refrigerants are limited or regulated. To alleviate the problems, new refrigerants with lower GWP and higher cycle performance must be developed and used. In this paper, calculated thermophysical properties of hydrofluoroolefin refrigerants using databases are evaluated with experimental data. Then, the fundamental cycle performance of air conditioning by using major refrigerants is studied based on their thermophysical properties. The results show that there is no adequate refrigerant for air conditioning applications. Heat pumps with new refrigerants including refrigerant mixtures must be developed as fast as possible. It leads to that HFC refrigerants must be used taking care until the new refrigerants will be available.

  • chapterNo Access

    Chapter 10: Flexible α-Fe2O3 Nanorod Electrode Materials for Sodium-Ion Batteries with Excellent Cycle Performance

    With the rise of flexible electronics, flexible rechargeable batteries have attracted widespread attention as a promising power source in new generation flexible electronic devices. In this work, α-Fe2O3 nanorods grown on carbon cloth have been synthesized through a facile hydrothermal method as binder-free electrode material. The electrochemical performance measurements show that α-Fe2O33 nanorods possess high specific capacitance and specific capacity retention of 119% after 100 cycles. The combination of low cost and excellent electrochemical performance makes α-Fe2O3 nanorods promising anode materials for sodium-ion batteries.

  • chapterNo Access

    EFFECT OF Fe ADDITION ON THE CYCLE PERFORMANCE OF FeS2 CATHODE FOR Li/FeS2 BATTERY

    The effect of Fe addition on the cycle performance of FeS2cathode for Li/FeS2cell was investigated. After cathode fabrication, additional compounds were not formed. In the case of Li/FeS2 cell without Fe, a large voltage drop was observed at initial discharge process. Also, the cell showed poor cycle performance until the 40th cycle. On the other hand, the Li/FeS2 cell with 10wt.% Fe delivered a higher the 1st discharge capacity of about 670mAh/g-FeS2 and it exhibited better cycle performance than the cell without Fe. Moreover, rate capability of the cell was improved by the addition of Fe in the FeS2cathode.