Cyclotomic classes of order 2 with respect to a product of two distinct odd primes pp and qq are represented in some specific forms and using these forms an alternate proof of Theorem 3 of [C. Ding and T. Helleseth, New generalized cyclotomy and its applications, Finite Fields Appl.4 (1998) 140–166] is given, when n=pqn=pq. Further, it is observed that these classes are related to ll-cyclotomic cosets, where Op(l)=ϕ(p)2Op(l)=ϕ(p)2 and Oq(l)=ϕ(q)Oq(l)=ϕ(q) such that gcd(ϕ(p)2,ϕ(q))=1ϕ(p)2,ϕ(q))=1. Finally, arithmetic properties of some families in Z[x]/〈xpq−1〉Z[x]/⟨xpq−1⟩ and hence in Fl[x]/〈xpq−1〉Fl[x]/⟨xpq−1⟩ are studied.