Potassium niobate KNbO3 and some compounds of (K1-xNax)NbO3 (x = 0.3, 0.4, 0.6, 0.7) ceramics powders were successfully prepared by the solid-state reaction method using a non-stoichiometric mixture of starting materials. A possible formation of these phases was proposed based on the experimental results. All of the prepared compounds were characterized using the X-ray diffraction method, and grain size has been calculated using SEM images, and their stoichiometry was obtained from the EDAX results.