MgB2 thin films were deposited at low temperature substrates, in situ, on c-plane sapphire substrates, with the aluminium nitride (AlN) buffer layers, using the multiple-target sputtering system. The magnetoresistivities were measured using dc-five probe method in applied magnetic field up to 9 Tesla. The upper critical field anisotropy, HC2(T) and irreversibility field Hirr(T) versus temperature were determined. The Hall coefficients RH are slightly temperature dependent and positive in the normal state. The critical temperature of 30–32 K and critical current density of 106-107A/cm2 at 4.2 K were obtained. Using extracted data, the coherence length ξo, anisotropic coefficient γ and penetration depth λL were calculated.