The problem of determining a complete set of invariants for characterizing the Clifford class of a central simple G-algebra over a field K is studied under the assumption that the algebra is simple ring. This is successful in the case of interior central simple G-algebras over K, and also when the inertia subgroup of the G-algebra is a direct factor of G. As an application of the latter, it is shown that if G is a finite abelian group, L is a Galois extension of K with Galois group G, and E is a G-algebra isomorphic to EndKV for some KG-module V, then the skew group ring of G over L ⊗K E is a split matrix algebra over K.