The temperature dependence of the NMR spin-lattice relaxation time is analyzed for preliminary evaluation of the correlation time of the local dynamics of the polymeric chain, for the molten polyisoprene and some polyisoprene-CCl4 solutions. Complementary information concerning this dynamics were obtained from the analyze of the ESR spectra recorded from the nitroxide molecules (2, 2, 6, 6, tetramethyl piperidin-1-yloxyl) dissolved in the polyisoprene-CCl4 solutions.