Low-energy Lorentz-invariant quantities could receive contributions from a fundamental theory producing small Lorentz-violating effects. Within the Lorentz-violating extension of quantum electrodynamics, we investigate, perturbatively, the contributions to the one-loop ffγ vertex from the CPT-violating axial coupling of a vector background field to fermions. We find that the resulting vertex function has a larger set of Lorentz structures than the one characterizing the usual, Lorentz-invariant, parametrization of the ffγ vertex. We prove gauge invariance of the resulting one-loop expression through a set of gauge invariant nonrenormalizable operators introducing new-physics effects at the first- and second-orders in Lorentz-violation, and which generate tree-level contributions to the ffγ vertex. Whereas loop contributions involving parameters that violate Lorentz-invariance at the first-order are CPT-odd, those arising at the second-order are CPT-even, so that contributions to low-energy physics are restricted to emerge for the first time at the second-order. In this context, we derive a contribution to anomalous magnetic moment (AMM) of fermions, which we use to set a bound on Lorentz-violation.