In this paper, we first propose two Chebyshev-type inequalities associated with the general fractional-order (Yang–Abdel–Aty–Cattani) integrals with the Rabotnov fractional-exponential kernel under the condition that μ and ν are synchronous functions. What is more, by the mathematical induction, we prove a new Chebyshev-type inequality in the case that (μi)i=1,…,n be n positive increasing functions. Finally, we introduce a novel Chebyshev-type inequality via the general fractional-order integrals with the Rabotnov fractional-exponential kernel under the condition that μ and ν are monotonic functions.