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Facile, controllable and efficient SERS substrate preparation has always been the focus project in the SERS field, especially the solid-state nanoarray substrate. Herein, a simple and convenient method for preparing a series of homogeneous Ag-stepped nanocone arrays (Ag-SNCAs) using polymer nanocompression printing is presented. By analyzing the 1162cm−1 characteristic peak of crystal violet (CV), the relative standard deviation (RSD) of the Raman intensity was only 4.71%. The detection limit of malachite green (MG) reached 0.001ppm, and it also has good SERS detection results for drug molecules such as melamine, methadone, morphine, methamphetamine and thiabendazole. This work provides a large area uniform and controllable preparation method of sharp cone nanostructure array, which has important application in plasmonic photocatalysis and deep light field regulations.
Multi-analyte chemical sensor aims to transform subtle variations in multiple analytes’ physical or chemical properties into distinct output signals. Chemically responsive nanostructure array (nanoarray) promises as a competitive sensor platform due to its robust physical properties, tunable chemical composition, and high surface area for analyte interaction. Specifically, the well-defined size, shape, and tunable surface structure and properties make it feasible to develop either new sensing modes on single device or integrated multi-modular sensors. In conjunction with the well-developed resistor-type sensors and sensor arrays, the complementary utilization of and intercorrelation with the electrochemical, optical, voltammetry modes in the multi-modular sensing strategies could provide multi-dimensional measurements to different analytes in a complex mixture form, where species information could be accurately and robustly separated from spatially collective responses. This review intends to provide a survey of the recent progress on multi-analyte sensing strategies and their unique structure design, as well as the related sensing mechanics in interaction of analytes and sensitizer and the behind mechanism for analytes’ differentiation.
Highly ordered crystalline and amorphous Si nanoarrays have been formed by using self-assembled monolayer of polystyrene nanospheres as a template followed by dry ion etching treatments. The template was removed by annealing at 8°C and pattern transfer process was revealed by atomic force microscopy. It was shown that the ordered Si nanotips with a height about 70–80 nm and an average lateral size around 150 nm can be obtained. Field emission with low threshold electric field (<10 V/μm) was demonstrated for both samples which can be attributed to the enhancement of local field due to the existence of surface nanostructures. Our results provide a simple and cheap way to make Si field emitters.
The hollow nanoarrays have great potential in both communication systems and monochromatic light conduction. At present, how to prepare the hollow nanoarrays quickly and efficiently is still a challenge. In this work, we introduce a kind of nanoarray supported by carbon nanotubes and oriented stretching by instantaneous Joule heating. The hollow nanoarrays have a small diameter, and are expected to enable single-mode transmission of light source signals, as well as the prospect of application in monochromatic photocatalysis. Therefore, the obtained hollow nanoarrays have a wide range of application prospects in the field of information transmission, catalysis and sensor.
Multi-analyte chemical sensor aims to transform subtle variations in multiple analytes’ physical or chemical properties into distinct output signals. Chemically responsive nanostructure array (nanoarray) promises as a competitive sensor platform due to its robust physical properties, tunable chemical composition, and high surface area for analyte interaction. Specifically, the well-defined size, shape, and tunable surface structure and properties make it feasible to develop either new sensing modes on single device or integrated multi-modular sensors. In conjunction with the well-developed resistor-type sensors and sensor arrays, the complementary utilization of and intercorrelation with the electrochemical, optical, voltammetry modes in the multi-modular sensing strategies could provide multi-dimensional measurements to different analytes in a complex mixture form, where species information could be accurately and robustly separated from spatially collective responses. This review intends to provide a survey of the recent progress on multi-analyte sensing strategies and their unique structure design, as well as the related sensing mechanics in interaction of analytes and sensitizer and the behind mechanism for analytes’ differentiation.