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The high density ferroelectric ceramic with composition near Pb0.99(Zr0.95Ti0.05)0.98Nb0.02O3 (PZT 95/5-2Nb) has been studied under dynamic loading. To characterize its ferroelectric-to-antiferroelectric(FE/AFE) phase transition under shock wave compression, reverse-impact experiments were conducted to determine the Hugoniot states of poled and unpoled PZT 95/5-2Nb, and the shock-induced depoling currents were examined in an external circuit under short-circuit conditions for the poled PZT 95/5-2Nb. The Hugoniot data and current results identify that the phase transition of FE/AFE has occured in the stress range of 0.4 GPa~1.8 GPa. In the phase transition stress range, the measured short-circuit currents show the increasing of rise time and the decreasing of final levels with the increase of shock stress.