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Titanium dioxide coatings were deposited by utilizing atmospheric plasma-spraying system. The agglomerated P25/20 nano-powder and different spraying parameters (e.g., Argon flow rate and spray distance) were used to determine their influences on the microstructure, crystalline structure, photo-absorption, and photo-catalytic performance of the coatings. The microstructure and phases of as-sprayed TiO₂ coatings were characterized by scanning electron microscope SEM and X-ray diffraction, respectively. Surface characteristics were investigated by Fourier Transform Infrared. Photo-catalytic efficiency of the elaborated samples was also determined in an environmental test chamber set-up and evaluated from the conversion rate of ethanol. The photo-absorption was determined by UV–Vis spectrophotometer. The as-sprayed TiO2 coating was photo-catalytically reactive for the degradation of ethanol. The photo-catalytic activity was influenced by spray conditions. It is found that the photo-catalytic activity is significantly influenced by anatase content, surface area, and surface state. The results showed that the argon flow rate has an influence on the microstructure, anatase content, and photo-catalytic activity of the TiO₂ coatings.

As the development of the "golden waterway" for the Yangtze River and the formation of the Three Gorges Reservoir area, the inland river shipping of chemical is increasing in China. At the same time, the risk of chemical leak accident is on the rising. Recent years, photo-catalyst has attracted great interest in environmental pollution treating for its unique properties. In order to improve its ability in pollution degradation, different kinds of doped TiO₂ are made in this work. Since the toxicity and transportation quantity, p-Xylene is researched as the aim chemical in this research. The influence of different catalyst, lighting time and reaction temperature to p-Xylene degradation rate are studied respectively in detail.

Cationic 2,9,16,23-tetrakis(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) and 20,21-bis(4-N,N,N-trimethylaminophenyl)-4,5,9,10,14,15-hexakis(4-t-butylphenyl)porphyrazinatozinc(II) were immobilized in MCM-41 silica by the use of an electrostatic interaction with the deprotonated silanol groups of MCM-41. From nitrogen adsorption isotherms, specific surface areas were estimated as 1031 and 702 m².g⁻¹ for MCM-41 and the composite of 2,9,16,23-tetrakis(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II), respectively. From pore-size distribution curves, the maximum pore diameter of MCM-41 and the composite were also estimated as 3.24 and 3.10 nm, respectively. These results revealed that 2,9,16,23-tetrakis(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) was immobilized in the mesopores of MCM-41. While 2,9,16,23-tetrakis(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) formed a dimer with increase in the amount of the complex in the composite, 20,21-bis(4-N,N,N-trimethylaminophenyl)-4,5,9,10,14,15-hexakis(4-t-butylphenyl)porphyrazinatozinc(II) only slightly formed a dimer in the composite, due to steric hindrance of its peripheral substituents. 1,3-diphenylisobenzofuran was photo-oxidized using the composites as the sensitizer in aerated acetonitrile. The reaction proceeded with singlet dioxygen generated by visible-light irradiation of the sensitizers. While the initial reaction rate with the composite of 20,21-bis(4-N,N,N-trimethylaminophenyl)-4,5,9,10,14,15-hexakis(4-t-butylphenyl)porphyrazinatozinc(II) increased in proportion to the increase in the amount of the complex, the initial reaction rate with the composite of 2,9,16,23-tetrakis(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) at first increased, but subsequently decreased due to the formation of the photo-inactive dimer.

Cationic 2,9,16,23-tetra(3-N,N,N-trimethylaminoethyloxy)phthalocyaninatozinc(II) (complex 1) and 2²,2³-di(4-N,N,N-trimethylaminophenyl)benzo[b]-7,8,12,13,17,18-hexa(4-t-butylphenyl) porphyrazinatozinc(II) (complex 2) were loaded on the surface of silica gel by use of an electrostatic interaction with deprotonated silanol groups of silica gel. While complex 1 formed its dimer with increase in the amount of the complex in the composite, complex 2 hardly formed the dimer in the composite due to the steric hindrance of its peripheral substituents. 1,3-diphenylisobenzofuran was photo-oxidized using the composites as the sensitizer in aerated methanol. The reaction proceeded with singlet dioxygen generated by the visible-light irradiation upon the sensitizer. While the initial reaction rate with the composite of complex 2 steadily increased in accordance with increase in the amount of the complex, that with the composite of complex 1 at first increased, but subsequently decreased due to the formation of the photo-inactive dimer. Bilirubinditaurate was also photo-oxidized using the composites as the sensitizer in an aerated aqueous solution. The reaction proceeded with superoxide instead of singlet dioxygen. The relationship between the initial reaction rate and the amount of the complex was similar to that in methanol.