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We present the polarized reflection spectra of several MPcs (M≡Co, Ni, Cu, Zn, Pb) in the Q-band region and interpret them based on conventional exciton theory. We compare the polarized reflection spectra of the phthalocyanine radical salts NiPc(AsF₆)_0.5, H₂Pc(AsF₆)_0.67 and LiPc and interpret the new absorption band near the Q-band using the relationship between the degree of oxidation and the intensity of this new band. Based on the pressure dependence of this new band and the diagnostic phonon modes, we prove a pressure-induced charge transfer in NiPc(AsF₆)_0.5. A metal–insulator phase transition is predicted from the analysis of the plasmon absorption and is confirmed by the high-pressure electrical resistivity. We propose the origin of the pressure-induced charge transfer and the mechanism of the metal–insulator transition. We find the optical transition associated with the 3d_z2 band in the reflection spectrum of CoPc(AsF₆)_0.5, which is proved by comparison with the mixed crystals Co_xNi_{1 − x}Pc(AsF₆)_0.5. A new weak intermolecular optical transition is found through the resonance enhancement of a local phonon in the mixed crystals Co_xNi_{1 − x}Pc(AsF₆)_0.5.

Pure and Al doped nanocrystalline ZnO films have been prepared on Hydrogen terminated Si(100) substrates by nebulized spray pyrolysis. The dependence of the structural, compositional and electrical properties were investigated using XRD, EDX, AFM and spectrophotometer. The X-ray diffraction data coincide well with the pattern of ZnO reported with the Standard Database. Films annealed at higher temperatures show better orientation, as revealed from X-ray diffraction patterns. Annealing the films in air improved the electrical properties. From the I-V characteristics, the nonlinear coefficient α value has been estimated. Reflectance measurements show good reflectance in the IR region for pure ZnO films, and Al doping improved the reflectance values.

Quantum and classical components are blended together in this proposed theoretical model for describing multiple quantum well solar cells (MQWSC) in a p-i-n architecture. The model characteristics are: the use of transfer matrix as a quantum method for finding allowed energies in the coupled quantum wells, the connection of the absorption coefficient in the confined 2D structure to the one in the bulk semiconductor, and the treatment of the whole cell as a pseudo-homogeneous media to determine its reflectance. The resulted model is intended to be a working tool to assess electro-optical properties of MQWSC. Numerical results which relate the performance of the MQWSC to its structure are reported.

In this work, numerical calculations and simulation based on Transfer Matrix Method have been presented to investigate a model solar cell structure. New four-layered structure containing different types of semiconductor has been presented, analyzed and discussed. The average reflectance and average transmittance in the visible light are derived and plotted versus the operating wavelength at different physical parameters. The obtained results show that the proposed structure is a promising candidate to be used for designing future solar cell structures.

Copper (Cu) nanowire arrays embedded in anodic aluminium oxide films (AAO) on aluminium substrate have been synthesized by alternating current electrochemical deposition. Two-step anodization process has been performed to get the through-hole AAO with ordered nanochannels in 0.3M oxalic acids at DC voltages 30, 40, 50 and 60V, respectively. Structural characterization of the Cu nanowires has been analyzed by scanning electron microscopy (SEM) and X-ray diffraction (or) X-ray diffractometer (XRD). Our SEM analysis has revealed that the diameters of vertically oriented Cu nanowires are 15, 25, 45 and 60nm and the length of Cu nanowires having high packing density is about 15$\mu$m. XRD measurement has indicated that polycrystalline Cu nanowires prefer growth orientation along the (111) direction. Optical measurements show that reflection of the Cu nanowires/AAO on aluminium reduces with decreasing diameter of the Cu nanowires. This effect can be associated with increased light scattering from metal nanoparticles near their localized plasmon resonance frequency depending on the size and shape of the nanoparticles.

Zinc oxide and germanium multilayer films have been deposited on glass substrate using electron beam evaporation and resistive heating system, respectively, for alternate layers. The structural optical and electrical parameters have been investigated for the deposited films. The layer formation was confirmed by employing Rutherford back-scattering technique. Optical properties exhibit quantum confinement effect by showing the separate band gaps for ZnO and Ge. Electrical conductivity increases due to combined effect of all six layers (six alternate layers of Ge and ZnO).