Let R be a symmetric and (α,δ)-compatible ring. In this paper, we first specify the zero-divisor elements of the near-ring R0[x;α,δ]. We prove that if R is an α-rigid ring, then the set of all zero-divisor elements of the near-ring R0[x;α,δ] forms an ideal of R0[x;α,δ] if and only if Z(R) is an ideal of R and R has the right Property (A). Also, we are interested in studying the zero-divisor graph of R0[x;α,δ] which is denoted by Γ(R0[x;α,δ]). It is shown that diam(Γ(R0[x;α,δ]))∈{2,3}, and if R is not reduced, then annR({a,b})∩Nil(R)≠0 for each a,b∈Z(R) if and only if diam(Γ(R0[x;α,δ]))=2. Moreover, we characterize the units, the clean elements, the regular elements, the nilpotent elements and also the π-regular elements of the near-ring R0[[x;α]], where R is a reversible and α-compatible ring and Nil(R) is a countable locally nilpotent ideal of R. Finally, we prove that the set of all π-regular elements of R0[[x;α]] forms a semigroup, where R is a reversible and α-compatible ring and Nil(R) is a countable locally nilpotent ideal of R.