For a *-ring AA, we associate a simple undirected graph Γ*(A)Γ∗(A) having all nonzero left zero-divisors of AA as vertices and, two vertices xx and yy are adjacent if xy*=0xy∗=0. In case of Artinian *-rings and Rickart *-rings, characterizations are obtained for those *-rings having Γ*(A)Γ∗(A) a complete graph or a star graph, and sufficient conditions are obtained for Γ*(A)Γ∗(A) to be connected and also for Γ*(A)Γ∗(A) to be disconnected. For a Rickart *-ring AA, we characterize the girth of gr(Γ*(A))gr(Γ∗(A)) and prove a sort of Beck’s conjecture.