An updated version of the Regional Acid Deposition Model (RADM) driven by meteorological fields derived from the Chinese Regional Climate Model (CRegCM) is used to simulate seasonal variation of tropospheric ozone over eastern China. The results show that:
Peak O3 concentration area moves from southern to northern China in response to the shifting of solar perpendicular incidence point from south to north.
In eastern China, the highest O3 month-average concentration occurs in July, the lowest in January, and intermediate values in April and October. The pattern mainly depends on solar radiation, the O3 concentration precursors of NOx and NMHC, and the ratio of NMHC/NOx.
Diurnal variations of O3 over eastern China are well defined. O3 concentration increases with the rising sun, reaching its maximum at noon and then falling off. The range of variation is highest in summer (40 × 10−9 in volume fraction) and lowest in winter (20 × 10−9 in volume fraction).
Diurnal variations of O3 over western China are not as clear. The range of variation is less than 10 × 10−9 in volume fraction.
NOx concentration increases as its emission increases. In January, surface O3 decreases as NOx increases. In July, O3 generally increases over the country. In April and October, O3 decreases in northeastern China, northern China and Sichuan province but increases in other areas.