Recently observed heavy quark exotic XYZ mesons stimulated heated discussions about their structures. In the molecule picture, we discuss the spin of the heavy quark pair in an S-wave meson-antimeson state, whose value is either 1 or 0. We find two rules that the spin is only 1 in the heavy quark limit. From the conservation of the
spin, one may analyze the charmonium products from strong decays. The selection rules give constraints on the products.