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We have used the lowest order constrained variational (LOCV) method to calculate some ground-state properties of polarized liquid 3 He at zero temperature with the spin-dependent correlation function employing the Lennard–Jones and Aziz pair potentials. We have seen that the total energy of polarized liquid 3He increases with increasing polarization. For all polarizations, it is shown that the total energy in the spin-dependent case is lower than the spin-independent case. We have seen that the difference between the energies of spin-dependent and spin-independent cases decreases by increasing the polarization. We have shown that the main contribution of the potential energy comes from the spin-triplet state.
By considering a spin dependence for the correlation function, the thermodynamic properties of normal liquid 3He have been investigated by employing a lowest order constrained variational approach. It is seen that the spin-singlet state has a smaller contribution in the potential energy of normal liquid 3He with respect to the spin-triplet state. It is seen that at high temperatures, the free energy of normal liquid 3He in cases of spin-dependent and spin-independent correlation functions are nearly identical. The equations of state of these two cases are nearly similar too.