Based on the observation of the long-lived isotopes of roentgenium, 261Rg and 265Rg(Z = 111, t1/2≥108y) in natural Au, an experiment was performed to enrich Rg in 99.999% Au. 16 mg of Au were heated in vacuum for two weeks at a temperature of 1127°C(63°C above the melting point of Au). The content of 197Au and 261Rg in the residue was studied with high resolution inductively coupled plasma-sector field mass spectrometry (ICP-SFMS). The residue of Au was 3×10-6 of its original quantity. The recovery of Rg was a few percent. The abundance of Rg compared to Au in the enriched solution was about 2×10-6, which is a three to four orders of magnitude enrichment. It is concluded that the evaporation rate of Rg from an Au matrix in vacuum at 63°C above the Au melting point is lower than that of Au. This experiment reinforces our first observation of Rg in a terrestrial material. As before it is concluded that a long-lived isomeric state exists in 261Rg and that it probably belongs to a new class of isomeric states, namely high spin (K-type) super- or hyperdeformed isomeric states.