In an earlier paper, Alvarez, Alvarez-Gaumé, Barbón and Lozano pointed out, that the only way to "flatten" negative curvature by means of a T-duality is by introducing an appropriate, non-constant NS–NS two-form B. In this paper, we are investigating this further and ask, whether it is possible to T-dualize AdSd space to flat space with some suitably chosen B. To answer this question, we derive a relationship between the original curvature tensor and the one of the T-dualized metric involving the B-field. It turns out that there is one component which is independent of B. By inspection of this component, we show that it is not possible to dualize AdSd to flat space irrespective of the choice of B. Finally, we examine the extension of AdS to an AdS5 × S5 geometry and propose a chain of S- and T-dualities together with an SL(2, ℤ) coordinate transformation, leading to a dual D9-brane geometry.