Narrow Results

Total suspended particulate (TSP) samples were collected at the west-facing slope (altitude 700 m) of Mt. Moriyoshi in northern Japan, from 24 – 27 June (non-snow-clad period) and 11 – 14 December (snow-clad period) in 1996, with a one-hour sampling interval. The elemental composition and particle shape of TSP samples were determined and/or observed by Particle Induced X-ray Emission (PIXE), a Scanning Electron Microscope (SEM) combined with Energy Dispersive X-ray (EDX) analysis. In the hourly TSP samples collected during the non-snow-clad period, 27 elements were determined. Na, Mg, Al, Si, S, K, Ca and Fe were found to be the major elemental components. On the other hand, 25 elements, excluding Nd and Mo, were found in the snow-clad period samples, and Cl is a dominant element, i.e., a major element, of the snow-clad period samples, unlike the non-snow-clad period. Comparing the arithmetic means of concentrations of major elements in TSP for non-snow-clad and snow-clad periods, Mg, Al, Si, K, Ca and Fe levels in the snow-clad period are 2 – 4 times as much as those in the non-snow-clad period, and 30 times for Na. S is similar. For temporal variation patterns of element concentrations, the non-snow-clad period is different from the snow-clad period. Al, S, Ca, Ti, Fe, Zn and Pb are similar throughout the non-snow-clad period, and Al, Si, Ca and Fe are similar throughout the snow-clad period. With the aid of SEM and EDX analysis, aggregates of car exhaust particles, soil particles and plant spores were observed in the non-snow-clad period samples. In the snow-clad period samples, small silicon-rich spherical particles, aggregates of car exhaust particles and soil particles were observed.

Total suspended particulate (TSP) samples were collected along a highway (Barajima air pollution monitoring station) in the center of Akita City in northern Japan, from 9 – 11 May, 1996 (non-snow-clad period) and 7 – 9 February, 1997 (snow-clad period), with a one-hour sampling interval, The elemental composition and particle shape of TSP samples were determined and / or observed by Particle Induced X-ray Emission (PIXE) and a Scanning Electron Microscope (SEM) combined with Energy Dispersive X-ray (EDX) analysis. In the hourly TSP samples collected during the non-snow-clad period, 26 elements were determined. Na, Mg, Al, Si, S, Cl, K, Ca and Fe are the major components. On the other hand, 24 elements, excluding As, Rb and Nb, are found in the snow-clad period samples, and Gallium is only found in the snow-clad period samples. Dominant elements, i.e., major components, of the snow-clad period were the same as the non-snow-clad period. Comparing the arithmetic means of major elemental concentrations in TSP for the non-snow-clad and snow-clad periods, Na, Mg, Al, Si and Fe are similar. However, S and Ca levels in the non-snow-clad period samples were 4 and 6 times higher than those in the snow-clad period samples, respectively, while Cl and K levels in the snow-clad period samples were 1.5 and 2 times higher than those in the non-snow-clad period, respectively. In the non-snow-clad period, the temporal variation pattern of total elemental amount was consistent with the variation pattern of NO and CO, which are pollutants used to observe the effects of automobile exhaust gas, and it was comparatively consistent with the variation pattern of SPM. On the other hand, in the snow-clad period, the temporal variation pattern of total elemental amount was not consistent with the variation pattern of NO and CO when the wind was blowing from the southeast, so the TSP may be strongly influenced by wind direction and wind velocity in addition to automobile traffic. Factor analysis allowed us to identify four major sources, with automobile emission, industry and soil being the major contributors. With the aid of SEM and EDX analysis, aggregates of diesel exhaust particles (DEP), soil particles and small silicon-rich spherical particles were observed in the non-snow-clad and snow-clad period samples.

Total suspended particulate (TSP) samples were collected from three areas (commercial, residential and agricultural) in and near Akita City in northern Japan, from May – June 1996 (non-snow-clad period) and January – February 1997 (snow-clad period), over three days with a one-hour sampling interval for each area. The elemental composition and particle shape of TSP samples were determined and/or observed by Particle Induced X-ray Emission (PIXE) and a Scanning Electron Microscope (SEM) combined with Energy Dispersive X-ray (EDX) analysis. In the hourly TSP samples collected during the non-snow-clad period, 23 elements were determined for each area, and Na, Mg, Al, Si, S, Cl, K, Ca and Fe were the major components. On the other hand, 25 elements, excluding As and Rb, were found in the snow-clad period samples, and P, Ga, Nb and Mo were only found in the snow-clad-period samples. Dominant elements, i.e., major components, of the snow-clad period were the same as the non-snow-clad period. Comparing the arithmetic means of elemental concentrations in TSP for the non-snow-clad and snow-clad periods, in the commercial area the elemental concentrations in the snow-clad period were the same or lower than those in the non-snow-clad period, with the concentrations of Na, Mg, Al, Si, S, K, Ca, Ti and Fe in particular being markedly lower. In the residential area the concentrations of Na, Mg and Cl were markedly higher in the snow-clad period than in the non-snow-clad period, while the concentrations of the other elements were the same or only slightly lower. In the agricultural area, the concentrations of Na and Cl were markedly higher in the snow-clad period relative to the non-snow-clad period, and the concentrations of the other elements, except for P, were low. The concentrations of the major elements and Pb were particularly low. Thus, in the residential and agricultural areas the effect of northwesterly winter wind on TSP can be observed by Cl, and it is conjectured that soil particles rising up into the air is inhibited by snow accumulation. Soil particles rising up into the air seems to be inhibited by snow accumulation in the commercial area as well. With the aid of SEM and EDX analysis, aggregates of diesel exhaust particles (DEP), soil particles and small silicon-rich spherical particles were observed in the non-snow-clad and snow-clad period samples for each area. In addition, small aluminum-rich and iron-rich spheres were observed during the non-snow-clad period in the commercial area. Zinc-rich fiber was observed during the non-snow-clad period in the residential area.

Total suspended particulate (TSP) samples were collected from three areas (commercial, residential and agricultural) in and near Akita City in northern Japan, October 1996 (rice straw burning period), over three days with a one-hour sampling interval for each area. The elemental composition and particle shape of TSP samples were determined and/or observed by PIXE and a Scanning Electron Microscope (SEM) combined with Energy Dispersive X-ray (EDX) analysis. In the hourly TSP samples collected during the rice straw burning period, values of 24 elements were determined for each area, and Na, Mg, Al, Si, S, K, Ca and Fe were the major components. Comparing the arithmetic means of elemental concentrations in TSP for the rice straw burning and non-snow-clad period (May – June 1996), in the residential and agricultural areas the Si concentration in the rice straw burning period was approximately two times that in the non-snow-clad period, and K and Ca concentrations in the rice straw burning period were a little higher than those in the non-snow-clad period. In the residential and agricultural areas, change in SPM concentration and change in Si, K and Ca concentrations were in relative agreement during the hours that smoke from rice straw burning was present in the atmospheric space. With the aid of SEM- EDX analysis, many cubic particles were observed for almost all hourly TSP samples. The cubic particles were of the silicon-rich type, and their morphology was rice straw fragments or aggregation of fragments.