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Lanthanide macrocyclic complexes: from molecules to materials and from materials to devices

Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), Université de Bourgogne, UMR CNRS 6302, 9 avenue A. Savary, F-21078 Dijon, France

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Pierre Gaudillat

Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), Université de Bourgogne, UMR CNRS 6302, 9 avenue A. Savary, F-21078 Dijon, France

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Jean-Moïse Suisse

Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB), Université de Bourgogne, UMR CNRS 6302, 9 avenue A. Savary, F-21078 Dijon, France

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https://doi.org/10.1142/S1088424613300048Cited by:45 (Source: Crossref)

Abstract

In the present review, we show how the chemistry of lanthanide macrocyclic complexes, which began almost 50 years ago in Russia, is still very active. Additionally to bisphthalocyanines complexes, triple-decker, but also quadruple- and quintuple-decker complexes have been synthesized via new chemical routes. The driving force for the development of this chemistry arises from the wide range of possible applications. Owing to their very high conductivity, compared to that of monophthalocyanines, LnPc₂ and Ln₂Pc₃ complexes are used as molecular semiconductors in electronic devices. The radical nature of LnPc₂ complexes makes them easily oxidized and reduced. This is the reason why they are particularly promising materials for the development of new chemical sensors, associated with both conductimetric and optical transducers.

Dedicated to Professor Evgeny Luk'yanets on the occasion of his 75th birthday

Keywords:

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