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Position isomer separation of non-peripheral substituted zinc dibenzo-di(3,4-pyrido)porphyrazines

Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

Corresponding author, Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan.

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TAKU KATO

Department of Applied Molecular Chemistry, College of Industrial Technology, Nihon University, 1-2-1 Izumi-cho, Narashino-shi, Chiba-ken 275-8575, Japan

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, and

MICHAEL J. COOK

School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, UK

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https://doi.org/10.1002/jpp.391Cited by:27 (Source: Crossref)

Abstract

The cyclotetramerisation products from the 1,8-diazabicyclo[5,4,0]undec-7-ene catalysed reaction of a 1:1 mol mixture of 3,6-didecylphthalonitrile and 3,4-dicynopyridine in the presence of zinc chloride have been isolated by chromatography. The fractions comprise zinc octadecylphthalocyanine and compounds in which one, two, three and four pyridinoid rings replace the didecylbenzenoid moiety. The zinc bis(1,4-didecylbenzo)bis(3,4-pyrido)porphyrazine fraction was separated further into four sub-fractions and the components have been characterised by 400 MHz proton nuclear magnetic resonance spectroscopy, visible region spectroscopy, fluorescence spectroscopy and by cyclic voltammetry.

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