We study the pre-Lie algebra of rooted trees (𝒯,→) and we define a pre-Lie structure on its doubling space (V,⇝). Also, we find the enveloping algebras of the two pre-Lie algebras denoted, respectively, by (ℋ′,⋆,Γ) and (𝒟′,⋆,χ). We prove that (𝒟′,⋆,χ) is a module-bialgebra on (ℋ′,⋆,Γ) and we find some relations between the two pre-Lie structures.