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In the 21st century, understanding the mechanism of high-temperature superconductivity has emerged as a pinnacle achievement in condensed matter physics, capturing the lifelong interest of numerous physicists. This paper endeavors to offer a theoretical elucidation for this mechanism, advancing the broader field of physics. Recognizing that high-temperature superconductivity is an aspect of condensed matter physics — underpinned by Maxwell’s classical electromagnetic theory — we turn to theoretical mechanics and field theory, which are foundational perspectives in the contemporary scientific era. By framing Maxwell’s classical electromagnetic theory within the context of theoretical mechanics and field theory, this paper not only sheds light on the mechanism of high-temperature superconductivity but also recasts Maxwell’s theory within a purer theoretical mechanics and field theory domain. This represents a paradigmatic shift and cognitive transformation in physics. Furthermore, leveraging this theoretical mechanics and field theory interpretation of electromagnetic phenomena, we discern that electromagnetic phenomena can be more aptly explained without resorting to the concepts of charges and electric fields, leading to a reinterpretation of Coulomb’s law. We propose that protons and electrons might exist as entities devoid of charge-specific attributes and negate the possibility of a strongly correlated particle system within them.

Based on the fractal geometry science and the model of flow friction resistance when fluid flows through rough microcapillaries, the formula of diffusion layer thickness and the spatial charge density distribution of the pipe were derived. The relationship between the amount of space charge and the structural parameters of rough elements, relative roughness, liquid conductivity, pipeline diameter, and other physical quantities was discussed. It was found that the height of rough elements is directly proportional to the thickness of the diffusion layer, and also positively proportional to the amount of current. The predicted results of the model are in good agreement with existing models and various published experimental data, verifying the accuracy and reliability of the model.

Density functional theory calculations are performed to provide a molecular-level understanding of the mechanism of mercury adsorption on sulfuric acid-impregnated carbonaceous surface. The carbonaceous surface is modeled by a nine-fused benzene ring in which its edge carbon atoms on the upper side are unsaturated to simulate the active sites for reaction. SO₄ clusters with and without charge are examined to act as the representative species to model the sulfuric acid absorbed on the carbonaceous surface. All of the possible approaches of SO₄ clusters with and without charge on the carbonaceous surface are conduced to study their effects on mercury adsorption. The results suggest that sulfuric acid effect on the mercury adsorption capacity of the carbonaceous surface is very complicated, and it depends on a combination of concentration and charge of SO₄ cluster. SO₄ cluster presents a positive effect on mercury adsorption on the carbonaceous surface, but higher concentration of SO₄ cluster decreases the adsorption capacity of the carbonaceous surface for mercury removal because there is considerable competition for active sites between Hg and SO₄ cluster. Since all of the possible approaches of mercury on the carbonaceous surface with cluster, excluding one that mercury is adsorbed at bridge active site, can lead to the decrease in the adsorption energies of mercury on the carbonaceous surface, cluster presents a negative effect on the capacity of the carbonaceous surface for mercury adsorption regardless of the concentration of cluster. The results also indicate that SO₂ cluster and surface oxygen complex can be formed from SO₄ cluster with or without charge if mercury is adsorbed at bridge active site, which facilitates the mercury removal for the carbonaceous surface.

Judiciously designed phthalocyanines (Pcs), such as silicon-Pc bis(3,5-diphenyl)benzoate (1c), with axial substituents which prevent aggregation, can self-assemble to form ordered nanoporous films on electrode surfaces. In this paper, complementary techniques such as Scanning Kelvin Nanoprobe (SKN) microscopy, Atom Force Microscopy (AFM) and electrochemical measurements are used to demonstrate that films formed by silicon-Pc bis(3,5-diphenyl)benzoate allow size- and charge- selective transport of probe molecules through well-defined intermolecular cavities. In contrast, the analogs silicon-Pc bis(4-tert-butylbenzoate) (1a) and silicon-Pc bis(3-thienyl)acetate (1b) have different film morphologies when solvent-cast in the same manner and block the electrode surface. The role of the different axial substituents in orienting the molecules on the substrate is discussed.