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Based on the first-principles method of density functional theory and the transition state theory, the adsorption, occupancy and diffusion behaviors of H atoms in LaFeO3(010) surface with O vacancy are investigated. It is found that, for the LaFeO3(010) surface with O vacancy, the H atom prefers to adsorb on the O atom and also could adsorb on the Fe atom; the adsorption energy of H atom in the surface layer is the biggest, while the adsorption energy decreases with the H atom in-depth diffusion to the bulk; the diffusion of H atoms from the surface layer to the bulk phase is a process of progressive rotation around the O atom, and the stepwise diffusion is more likely to occur than the direct diffusion. If the H atom can cross the barrier and diffuse from the surface to the subsurface, it will be more likely to diffuse inward. The presence of O vacancy can reduce the barrier for H atoms diffusion from the surface to the subsurface, and then improve the diffusion properties of the LaFeO3(010) surface system.
In this paper, some new lane-changing rules for one-way two-lane traffic with one work zone are proposed. Considering their velocities difference between the vehicle in the current lane and some vehicle behind/ahead in the target lane, and its own velocity, driver will choose to change lanes if necessary. Unlike some previous studies, one-way two-lane with one work zone is divided into three sections: symmetrical zone, conversion zone and work zone. In the conversion zone, the maximum velocity of vehicles in merge lane depends on the number of unsuccessful lane-changing. Based on the refined Nagel–Schreckenberg model, all vehicles update their corresponding velocities and positions in own respective lanes, employing open boundary conditions. The computer results show that the system has two states: unsaturated state and saturated state. In the saturated state, these vehicles on these two lanes have the same occupancy, which change steadily without inflection point when approaching the conversion zone, especially for upstream of the work zone. As one of the results of vehicle self-organization, the system can reach the saturated state in a short period of time as the injection probability increases. This saturated state can also spread across the conversion zone to the symmetrical zone. In the unsaturated state, one also finds that the velocity distribution can be consistent with the actual traffic conditions for upstream of the work zone. We selected three road sections with work zone to carry out field test, and the flow of these three road sections is basically consistent with the flow of the saturated state for the present model.
With one-tap check-ins, digital concierge services, voice-activated gadgets, chatbots, smart in-room technology, and advanced analytics, the hotel sector has been quickly embracing new technologies to meet and exceed consumer expectations and digitize the customer experiences. The traditional hotel management with internet-based customer service could not handle dynamic real-time data efficiently due to increased data volume. Thus, this work analyzes hotel management practices with the internet of things (IoT) and big data. The IoT and big data significantly impact the guest experience since businesses can provide consumers with unique services to their needs. Automated check-in and checkout, pre-booking, registration, and user-chosen payment methods are just a few self-services that improve the visitor experience. For enhancing visitor satisfaction and offering tailored services, this paper looks at how IoT and big data analytics can help the hotel sector. It moreover examines how IoT can be used within the business. This extended research finds excellent results in hotel management through IoT and big data. A client occupancy detection model (CODM) simulation scenario finds the best detection accuracy of 97.51%.