Characterizing the nature of single-particle states outside of double shell closures is essential to a fundamental understanding of nuclear structure. This is especially true for those doubly magic nuclei that lie far from stability and where the shell closures influence nucleosynthetic pathways. The region around 100Sn is one of the most important due to the proximity of the N=Z=50 magic numbers, the proton-drip line, and the end of the rp-process. However, owing to the low production rates, there is a lack of spectroscopic information and no firm spin-parity assignment for ground states of odd-A isotopes close to 100Sn. Neutron knockout reaction experiments on beams of 108,106Sn and 106Cd have been performed at the NSCL. By measuring gamma rays and momentum distributions from reaction residues, the spin of ground state and first excited state for 107,105Sn have been established. The results also show a degree of mixing in the ground states of the isotopes 108,106Sn between the d5/2 and g7/2 single particle-states and they are compared to reaction calculations. Single-, double-, and triple-neutron knockout reactions on the 106Cd beam have been observed. The spin-parity of 105Cd is already known, therefore, the measurement of the momentum distributions of the ground and first excited states of this residue is an important validation of the technique used for the light tin isotopes.